Generation of Long-lived singlet diradicals with pi-single bonded character
Singlet diradicals are key intermediates inprocesses involving homolytic bond-cleavage and formation reaction. Thus, thesinglet diradicals should be the short-lived intermediates due to the fastradical-radical coupling reaction.
In the present talk, I will talk about thelong-lived singlet 1,3-diradicals with p-single bonded character.
References
- Abe, Manabu; Ye, Jianfuai; Mishima, Megumi, Chem. Soc. Rev., (2012), 41, 3808-3820.
- Abe, M.; Iwakura, I.; Yabushita, A.; Yagi, S.; Liu, J.; Okamura, K.;Kobayashi, T. Chem. Phys. Lett., 2012, 527, 79-83.
- Yagi, S.; Hiraga, Y.; Takagi, R.; Abe, M.*, J. Physical Organic Chemistry,2011, 24, 894-901.
- Yabuno, Youhei; Hiraga, Yoshikazu; Takagi, Ryukichi;Abe, Manabu, Journal of the American Chemical Society, 2011, 133, 2592-2604.
- Takeshi Nakamura, Gagliardi, Laura; Abe,Manabu* J. Phys. Org. Chem., 2010, 23, 300-307.
- Nakamura, Takeshi; Takegami, Akinobu;Abe, Manabu* J. Org.Chem., 2010, 75, 1956-1960.
- Hamaguchi, Masashi, Nakaishi, Masahiro; Nagai, Toshikazu;Nakamura, Takeshi; Abe, Manabu.
- Abe, Manabu et al. Journal of theAmerican Chemical Society (2007), 129 (43), 12981-12988.
Date & Time
09-08-2012 12:00:00 to
Venue Seminar Room 219