After joining IISER TVM
25) Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ring.
R. Yadav,+ A. Maiti,+ M. Schorpp, J. Graf, F. Weigend, L. Greb
Nature Chem. 2024, accepted article. (link) (+ equal contribution).
24) Reactivity of [Cp*Fe(η5-As5)] towards Carbenes, Silylenes and Germylenes
S. Reichl, C. Riesinger, R. Yadav, A. Timoshkin, P. W. Roesky, M. Scheer
Angew. Chem. Int. Ed., 2024, 63, e202316117. (link)
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Before joining IISER TVM
23) Structural constraint effects on p-block elements: Recent advances
A. Maiti,+ R. Yadav,+ L. Greb
Adv. Inorg. Chem. 2023, 82, 261-299. (link) (+ equal contribution, book chapter)
22) Calix[4]pyrrolato-germane-(thf)2: Unlocking the Anti-van’t Hoff–Le Bel Reactivity of Germanium(IV) by Ligand Dissociation
R. Yadav,+ P. Janßen,+ M Schorpp, L Greb
J. Am. Chem. Soc., 2023, 145, 32, 17746-17754. (link) (+ equal contribution).
21) Reactivity of E4 (E4 = P4, As4, AsP3) towards low-valent Al(I) and Ga(I) compounds
M. Haimerl, M. Piesch, R. Yadav, P. W. Roesky, M. Scheer
Chem. Eur. J., 2022, 29, e202202529. (link)
20) Stimuli responsive silylene: Electromerism induced reversible switching between mono- and bis-silylene
R. Yadav, X. Sun, R. Köppe, M. T. Gamer, F. Weigend, and P. W. Roesky
Angew. Chem. Int. Ed., 2022, 61, e202211115. (link)
19) Calix[4]pyrrolato Stibenium: Lewis Superacidity by Antimony(III)-Antimony(V) Electromerism
M. Schropp,+ R. Yadav,+ D. Roth, L. Greb
Angew. Chem. Int. Ed., 2022, 61, e202207963. (link) (+ equal contribution).
18) Triple-decker complexes incorporating three distinct deck architectures
X. Sun, A. K. Singh, R. Yadav, D. Jin, M. Haimerl, M. Scheer, P. W Roesky
Chem. Commun., 2022, 58, 673-676. (link)
17) Base-stabilized formally zero-valent mono and diatomic molecular main group compounds
R. Yadav,* S. Sinhababu,* R. Yadav, S. Kundu*
Dalton trans., 2022, 51, 2170-2202. (link) (Review article), (* corresponding author).
16) Thermally activated delayed fluorescence and phosphorescence quenching in iminophosphonamide copper and zinc complexes
B. Goswami, T. J Feuerstein, R. Yadav, S. Lebedkin, P. J Boden, S. T Steiger, G. Niedner‐Schatteburg, M. Gerhards, M. M Kappes, P. W Roesky
Chem. Eur. J., 2021, 27, 61, 15110-15119. (link)
15) A Structural Diversity of Molecular Alkaline‐Earth‐Metal Polyphosphides: From Supramolecular Wheel to Zintl Ion
R. Yadav,+ M. Weber,+ A. K Singh, L. Münzfeld, J. Gramüller, R. M Gschwind, M. Scheer, P. W Roesky
Chem Eur. J., 2021, 27, 56, 14128-14137. (link) (+ equal contribution).
14) Nonanuclear zinc-gold [Zn3Au6] heterobimetallic complexes
R. Yadav, M. Dahlen, A. K Singh, X. Sun, M. T. Gamer, P. W Roesky
Dalton trans., 2021, 50, 24, 8558-8566. (link)
13) Application of the Redox‐Transmetalation Procedure to Access Divalent Lanthanide and Alkaline‐Earth NHC Complexes
N. Schwarz, X. Sun, R. Yadav, R. Köppe, T. Simler, P. W Roesky
Chem. Eur. J., 2021, 27, 50, 12857-12865. (link)
12) d/f‐Polypnictides Derived by Non‐Classical Ln2+ Compounds: Synthesis, Small Molecule Activation and Optical Properties
N. Reinfandt, N. Michenfelder, C. Schoo, R. Yadav, S. Reichl, S. N Konchenko, A. N Unterreiner, M. Scheer, P. W Roesky
Chem. Eur. J., 2021, 27, 29, 7862-7871. (link)
11) Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis
B. Goswami, T. J Feuerstein, R. Yadav, R. Köppe, S. Lebedkin, M. M Kappes, P. W Roesky
Chem. Eur J., 2021, 27, 13, 4401-4411. (link)
10) Neutral and cationic enantiopure group 13 iminophosphonamide complexes
B. Goswami, R. Yadav, C. Schoo and P. W. Roesky
Dalton Trans., 2020, 49, 675-681. (link)
9) 3d-4f Heterometallic Complexes by the Reduction of Transition Metal Carbonyls with Bulky LnII Amidinates
R. Yadav, Md E. Hossain, R. P. Paramban, T. Simler, C. Schoo, J. Wang, G. B. Deacon, P. C. Junk and P. W. Roesky
Dalton Trans., 2020, 49, 7701-7707. (link) (Hot article & front cover).
8) A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization
R. Yadav, B. Goswami, T. Simler, C. Schoo, S. Reichl, M. Scheer and P. W. Roesky
Chem. Commun., 2020, 56, 70, 10207-10210. (link)
7) Regioselective insertion of aluminium(I) in the cyclo-P5 ring of pentaphosphaferrocene
R. Yadav, T. Simler, B. Goswami, C. Schoo, R. Köppe, S. Dey and P. W. Roesky
Angew. Chem. Int. Ed., 2020, 59, 9443–9447. (link)
6) Highly selective substitution and insertion reactions of silylenes in a metal-coordinated polyphosphide
R. Yadav, T. Simler, S. Reichl, B. Goswami, C. Schoo, R. Köppe, M. Scheer and P. W. Roesky
J. Am. Chem. Soc., 2020, 142, 3, 1190–1195. (link)
5) A stable aromatic tetrasilacyclobutadiene dication
X. Sun, T. Simler, R. Yadav, R. Köppe and P. W. Roesky
J. Am. Chem. Soc., 2019, 141, 38, 14987–14990. (link)
4) Reaction of an arsinoamide with chloro tetrylenes: substitution and As –N bond insertion
X. Chen, T. Simler, R. Yadav, M. T. Gamer, R. Köppe and P. W. Roesky
Chem. Commun., 2019, 55, 9315-9318. (link)
3) Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls
R. Yadav, T. Simler, M. T. Gamer, R. Köppe and P. W. Roesky
Chem. Commun., 2019, 55, 5765-5768. (link) (Inside front cover).
2) Access to divalent lanthanide NHC complexes by redox-transmetallation from silver and CO2 insertion reactions
T. Simler, T. J. Feuerstein, R. Yadav, M. T. Gamer, R. Köppe and P. W. Roesky
Chem. Commun., 2019, 55, 222-225. (link)
1) Catalytic cyanosilylation using germylene stabilized platinum(II) dicyanide
M. K. Sharma, D. Singh, P. Mahawar, R. Yadav, and S. Nagendran
Dalton Trans., 2018, 47, 5943-5947. (link)