Dr Basudev Sahoo
Assistant Professor Grade I (Chemistry)
+91 (0)471 - 2778253
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Publications (from IISER TVM)
2024
38. Subham Das, Amit Dhibar, Basudev Sahoo* ACS Organic & Inorganic Au 2024 (accepted).
Strategic Synthesis of Sulfinamides as Versatile S(IV) Intermediates.
37. Sourav Biswas, Amit Pal, Milan Jena, Sakiat Hossain, Jin Sakai, Saikat Das, Basudev Sahoo,* Biswarup Pathak,* Yuichi Negishi* J. Am. Chem. Soc. 2024, doi: 10.1021/jacs.4c05678.
Luminescent Hydride-Free [Cu7(SC5H9)7(PPh3)3] Nanocluster: Facilitating Highly Selective C-C Bond Formation.
36. Pinku Prasad Mondal, Alvin Antony Chungath,† Malavika Krishnan,† Subham Das,† Aarya Mandodi, Basudev Sahoo* J. Org. Chem. 2024, doi: 10.1021/acs.joc.4c01326
Synthesis of Unsymmetrical 3,3'-Dialkyloxindole Boronic Esters from 3-Alkylidene-2-oxindoles Enabled by Copper Catalysis.
35. Subham Das, Pinku Prasad Mondal,† Amit Dhibar,† Aan Ruth, Basudev Sahoo* Org. Lett. 2024, 26, 3679–3684.
Unifying N-Sulfinylamines with Alkyltrifluoroborates by Organophotoredox Catalysis: Access to Functionalized Alkylsulfinamides and High-Valent S(VI) Analogues.
34. Pinku Prasad Mondal, Anagha Veluthanath Nair,† Megha Sasidaran,† Alvin Antony Chungath,† Satya Prakash Suman, Rositha Kuniyil,* Basudev Sahoo* Org. Lett. 2024, 26, 1458-1462.
Regioselective 1,2-Alkylboration of Alkylidenecyclopropanes: Access to Csp3-Enriched Cyclopropylboronic Esters.
33. Anish Kumar Das,‡ Sourav Biswas,‡ Amit Pal, Surya Sekhar Manna, Avirup Sardar, Pradip Kumar Mondal, Basudev Sahoo,* Biswarup Pathak* and Sukhendu Mandal* Nanoscale 2024, 16, 3583-3590.
A thiolated copper-hydride nanocluster with chloride bridging as a catalyst for carbonylative C–N coupling of aryl amines under mild conditions: a combined experimental and theoretical study
2023
32. Sandip Bag, Shubham Ojha, Sreelakshmi Venugopalan,§ Basudev Sahoo* J. Org. Chem. 2023. 10.1021/acs.joc.3c01149
Photocatalytic Alkylation/Arylative Cyclization of N-Acrylamides of N-Heteroarenes and Arylamines with Dihydroquinazolinones from Unactivated Ketones
31. Pinku Prasad Mondal, Subham Das, Sreelakshmi Venugopalan,§ Malavika Krishnan,§ Basudev Sahoo* Org. Lett. 2023, 25, 1441-1446.
Visible-Light-Photocatalyzed Dicarbofunctionalization of Conjugated Alkenes with Ketone-Based Dihydroquinazolinones
30. Pinku Prasad Mondal, Amit Pal, Subham Das, Sariga Mangalamundackal Vijayan, Anagha Veluthanath Nair, Shubham Ojha, Basudev Sahoo* Synlett 2023, 34, 1241-1246.
Organophotoredox-Catalyzed Oxidative C(sp2)-H Alkylation of N-Heteroarenes with Dihydroquinazolinones via C-C Bond Cleavage
2022
29. Amit Pal, Pinku Prasad Mondal, Fathima Niloofar, Basudev Sahoo* Eur. J. Org. Chem. 2022, 2022, e202201159.
Synthetic Strategies for Versatile Thioester Building Blocks
28. Pinku Prasad Mondal, Amit Pal, Athira K Prakash, Basudev Sahoo* Chem. Commun. 2022,58, 13202-13205.
Ketone-Derived 2,3-Dihydroquinazolinones in N-Heteroarene C-H Alkylation via C-C Bond Scission under Oxidative Metal Catalysis
2021
27. Dilsha Jinan, Pinku Prasad Mondal, Anagha V Nair, Basudev Sahoo,* Chem. Commun. 2021, 57, 13495-13505.
O-Protected NH-Hydroxylamines: Emerging Electrophilic Aminating Reagents in Organic Synthesis.
26. Sudhir K. Hota, Dilsha Jinan, Satya P. Panda, Rittwika Pan, Basudev Sahoo,* Sandip Murarka,* Asian J. Org. Chem. 2021, 10, 1848-1860.
Organophotoredox-Catalyzed Late-Stage Functionalization of Heterocycles.
25. Suman Pradhan, Sourav Roy, Basudev Sahoo,* Indranil Chatterjee,* Chem. Eur. J. 2021, 27, 2254-2269.
Visible-light Photoredox Catalysed Recent Advances in the Utilization of CO2 feedstock for Organic Synthesis.
Publications (from PhD and Postdocs)
2024
24. Jacob Davies, Julien R. Lyonnet, Bjørn Carvalho, Basudev Sahoo, Craig S. Day, Francisco Juliá- Hernández, Yaya Duan, Álvaro Velasco-Rubio, Marc Obst, Per-Ola Norrby,* Kathrin H. Hopmann,* Ruben Martin*
J. Am. Chem. Soc. 2024, 146, 1753-1759.
Kinetically-Controlled Ni-Catalyzed Direct Carboxylation of Unactivated Secondary Alkyl Bromides without Chain Walking.
2020
23. Marino Borjesson, Daniel Janßen-Müller, Basudev Sahoo, Yaya Duan, Xueqiang Wang, Ruben
Martin*
J. Am. Chem. Soc. 2020, 142, 16234-16239.
Remote sp2 C-H Carboxylation via catalytic 1,4-Ni Migration with CO2
22. Daniel Janßen-Müller, Basudev Sahoo, Shang-Zheng Sun, Ruben Martin*
Isr. J. Chem. 2020, 60, 195-206.
Tackling Remote sp3 C-H Functionalization via Ni-Catalyzed "chain-walking" Reactions
2019
21. Andreu Tortajada, Yaya Duan, Basudev Sahoo, Fei Cong, Georgios Toupalas, Antoine
Sallustrau, Olivieau Loreau,Davide Audisio, Ruben Martin*
ACS Catal. 2019, 9, 5897-5901.
A Catalytic Decarboxylation\Carboxylation Platform for Accessing Isotopically-Labeled
Carboxylic Acids.
20. Basudev Sahoo, Peter Bellotti, Francisco Juliá-Hernández, Qing-Yuan Meng, Stefano Crespi,*
Burkhard König,* Ruben Martin*
Chem. Eur. J. 2019, 25, 9001-9005.
Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel
Catalysis
2018
19. Basudev Sahoo, Carsten Kreyenschulte, Giovanni Agostini, Henrik Lund, Stephan Bachmann,
Michelangelo Scalone, Kathrin Junge, Matthias Beller*
A Robust Iron Catalyst for the Selective Hydrogenation of Substituted (Iso)Quinolones
18. Feng Chen, Wu Li, Basudev Sahoo, Carsten Kreyenschulte, Giovanni Agostini, Henrik Lund, Kathrin
Junge, Matthias Beller*
Angew. Chem. Int. Ed. 2018, 57, 14488-14492.
Hydrogenation of Pyridines using a Nitrogen-Modified Titania Supported Cobalt Catalyst
17. Weiping Liu, Basudev Sahoo, Kathrin Junge, Matthias Beller*
Acc. Chem. Res. 2018, 51, 1858-1869.
Cobalt Complexes as an Emerging Class of Catalysts for Homogeneous Hydrogenations
16. Weiping Liu, Basudev Sahoo, Anke Spannenberg, Kathrin Junge, Matthias Beller*
Angew. Chem. Int. Ed. 2018, 57, 11673-11677.
Tailored Cobalt-Catalysts for Reductive Alkylation of Anilines with Carboxylic Acids under Mild
Conditions
15. Basudev Sahoo, Matthew N. Hopkinson*
Angew. Chem. Int. Ed. 2018, 57, 7942-7944.
A Radical Revolution for Trifluoromethoxylation
2017
14. Feng Chen, Basudev Sahoo, Carsten Kreyenschulte, Henrik Lund, Min Zeng, Lin He, Kathrin Junge,
Matthias Beller*
Chem. Sci. 2017, 8, 6239-6246.
Selective Cobalt Nanoparticles for Catalytic Transfer Hydrogenation of N-Heteroarenes
13. Basudev Sahoo, Dario Formenti, Christoph Topf, Stephan Bachmann, Michelangelo Scalone,
Kathrin Junge, Matthias Beller*
ChemSusChem 2017, 10, 3035-3039.
Biomass-Derived Catalysts for Selective Hydrogenation of Nitroarenes
12. Basudev Sahoo, Annette-Enrica Surkus, Marga-Martina Pohl, Jörg Radnik, Matthias Schneider,
Stephan Bachmann, Michelangelo Scalone, Kathrin Junge, Matthias Beller*
Angew. Chem. Int. Ed. 2017, 56, 11242-11247.
A Biomass-Derived Non-Noble Cobalt Catalyst for Selective Hydro-dehalogenation of Alkyl and
(Hetero)Aryl Halides
2016
11. Matthew N. Hopkinson, Adrián Gόmez-Suárez, Michael Teders, Basudev Sahoo, Frank Glorius,*
Angew. Chem. Int. Ed. 2016, 55, 4361-4366.
Accelerated Discovery in Photocatalysis using a Mechanism-Based Screening Method
10. Adrian Tlahuext Aca, Matthew N. Hopkinson, Basudev Sahoo, Frank Glorius,*
Dual Gold/Photoredox-Catalyzed C(sp)-H Arylation of Terminal Alkynes with Diazonium Salts
2015
9. Basudev Sahoo, Matthew N. Hopkinson, Frank Glorius,*
Angew. Chem. Int. Ed. 2015, 54, 15545-15549.
External Photocatalyst-Free Visible Light-Mediated Synthesis of Indolizines
8. Basudev Sahoo, Jun-Long Li, Frank Glorius,*
Angew. Chem. Int. Ed. 2015, 54, 11577-11580.
Visible Light Photoredox-Catalyzed Semipinacol-Type Rearrangement: Trifluoromethylation/Ring
Expansion via a Radical- Polar Mechanism
7. Stella Helten, Basudev Sahoo, Philipp Müller, Daniel Janßen-Müller, Nicole Klein, Ronny Grünker,
Volodymyr Bon, Frank Glorius, Stefan Kaskel, Irena Senkovska,*
Microporous Mesoporous Mater. 2015, 216, 42-50.
Functional group tolerance in BTB-based Metal-Organic Frameworks (BTB – benzene-1,3,5-
tribenzoate)
6. Stella Helten, Basudev Sahoo, Volodymyr Bon, Irena Senkovska, Stefan Kaskel,* Frank Glorius,*
CrystEngComm 2015, 17, 307-312.
Copolymerisation at work: the first example of a highly porous MOF comprising a triarylborane-
based linker
2014
5. Chang Guo, Basudev Sahoo, Constantin G. Daniliuc, Frank Glorius,*
J. Am. Chem. Soc. 2014, 136, 17402−17405.
N-Heterocyclic Carbene Catalyzed Switchable Reactions of Enals with Azoalkenes: Formal [4+3]
and [4+1] Annulations for the Synthesis of 1,2-Diazepines and Pyrazoles
4. Matthew N. Hopkinson, Basudev Sahoo, Frank Glorius,*
Adv. Synth. Catal. 2014, 356, 2794-2800.
Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes
3. Jun-Long Li, Basudev Sahoo, Constantin G. Daniliuc, Frank Glorius,*
Angew. Chem. Int. Ed. 2014, 53, 10515-10519.
Conjugate Umpolung of β,β-Disubstituted Enals by Dual Catalysis with an N-Heterocyclic Carbene
and a Brønsted Acid: Facile Constryction of Contiguous Quaternary Stereocenters
2. Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius,*
Chem. Eur. J. 2014, 20, 3874-3886.
Dual Catalysis sees the Light: Combining Photoredox with Organo-, Acid and Transition Metal
Catalysis
2013
1. Basudev Sahoo, Matthew N. Hopkinson, Frank Glorius,*
J. Am. Chem. Soc. 2013, 135, 5505-5508.
Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Amino-arylation of
Alkenes
Book(s)
1. “Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-
Organic Frameworks”
Basudev Sahoo in Springer Theses (2017), DOI: 10.1007/978-3-319-48350-4. ISBN:
978-3-319-48349-8; ISBN:
978-3-319-48350-4 (eBook).
Patent(s)
1. “Nitrogen-Containing Biopolymer-Based Catalysts, a process for Their Preparation and Uses
Thereof”
Stephan Bachmann, Matthias Beller, Dario Formenti, Kathrin Junge, Basudev Sahoo, Michelangelo
Scalone, Christoph Topf,
US Patent (2019), Patent No. US20190381485A1.